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Modeling of Processes and Reactors for Upgrading of Heavy Petroleum

Modeling of Processes and Reactors for Upgrading of Heavy Petroleum by Jorge Ancheyta
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Part I Properties and Upgrading of Heavy Oils
Heavy Petroleum
Assay of Heavy Petroleum
Problems during Upgrading and Refining of Heavy Petroleum

Technologies for Upgrading of Heavy Petroleum
General Classification
Current Situation of Residue Upgrading
Hydrogen Addition Technologies
Carbon Rejection Technologies
Emerging Technologies
Combination of Upgrading Technologies
Combination of Both Hydrogen Addition and Carbon Rejection Technologies

Part II Modeling of Noncatalytic Processes
Modeling of Visbreaking
Process Description
Types of Visbreaking
Process Variables
Reactor Modeling

Modeling of Gasification
Types of Gasifiers
Process Variables
Process Description
Chemistry and Thermodynamics
Modeling of the Gasifier
Simulation of the Gasifier

Modeling of Coking
Coking Processes
Process Description
Process Variables
Fundamentals of Coking
Kinetics of Coking
Correlations to Predict Coking Yields

Noncatalytic (Thermal) Hydrotreating
Results and Discussion

Part III Modeling of Catalytic Processes
Modeling of Catalytic Hydroprocessing
Process Description
Types of Reactors
Process Variables
Modeling of Hydrotreating of Heavy-Oil-Derived Gas Oil

Modeling and Simulation of Heavy Oil Hydroprocessing
Description of the IMP Heavy Oil Upgrading Technology
Experimental Studies
Modeling Approach
Data Fitting
Simulation of the Bench-Scale Unit
Scale-Up of Bench-Unit Kinetic Data
Simulation of the Commercial Unit

Modeling of Bench-Scale Reactor for HDM and HDS of Maya Crude Oil
The Model

Modeling of Ebullated-Bed and Slurry-Phase Reactors
Characteristics of Ebullated-Bed Reactor
EBR Commercial Technologies
Modeling of Ebullated-Bed Reactor
Modeling of Slurry-Phase Reactors
Kinetic Study for Hydrocracking of Heavy Oil in CSTR
Final Remarks

Modeling of Hydrocracking by Continuous Kinetic Lumping Approach
Continuous Kinetic Lumping Model
Step-By-Step Example for Application of The Model
Modeling Hydrocracking of Maya Crude Oil
Modeling the Effect of Pressure and Temperature on the Hydrocracking of Maya Crude Oil
Modeling Simultaneous HDS and HDC of Heavy Oil
Significance of Parameters of Continuous Kinetic Lumping Model

Correlations and Other Aspects of Hydroprocessing
Correlations to Predict Product Properties during Hydrotreating of Heavy Oils
Hydrogen Consumption during Catalytic Hydrotreating
Real Conversion and Yields from Hydroprocessing of Heavy Oils Plants
Calculation of Fresh-Basis Composition from Spent Catalyst Analysis
Use of Probability Distribution Functions for Fitting Distillation Curves of Petroleum

CRC Press; January 2013
551 pages; ISBN 9781439880463
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Title: Modeling of Processes and Reactors for Upgrading of Heavy Petroleum
Author: Jorge Ancheyta
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