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Organotransition-Metal Chemistry

Organotransition-Metal Chemistry by Yoshio Ishii
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Synthesis of Organotransition Metals.- Metallocarboranes: Past, Present, and Future.- Novel Rhodium and Palladium Complexes with Benzoyl and Thiobenzoyl Isocyanates as Ligands.- Polycyanovinyl Transition Metal Derivatives.- A New Preparation of Organocopper(I)-Isonitrile Complexes and Their Reactions.- An Unusual Behavior of ?-Vinyl Alcohol Complexes of Transition Metals.- The Mode of Formation of Transition Metal to Carbon Bonds by Oxidative Addition.- Organoactinides: Coordination Patterns and Chemical Reactivity.- Recent Developments in Chemistry of Organolanthanides and Organoactinides.- Catalysis by Organotransition Metals.- Mechanisms of Homogeneous Catalytic Hydrogenation and Related Processes.- Homogeneous Catalysis of Nickel Complexes. Oligomerization, Polymerization and Some Related Reactions of Diolefins.- Homogeneous Catalytic Activation of Hydrocarbons.- Metallocycles as Intermediates in Organotransition-Metal Reactions.- Sequential Multistep Reactions Catalyzed by Polymer-Bound Homogeneous Ni, Rh, and Ru Catalysts.- Kinetic and Mechanism of Reactions and Catalysis of Organotransition Metals.- Concerted Reactions of Organic Ligands on Transition Metals.- The Role of the Transition Metal in Catalyzing Pericyclic Reactions.- Reactions of Transition Metal Dihydrides. Mechanism of Reactions of Dihydrido-bis(?-cyclopentadienyl)-molybdenum with Various Unsaturated Compounds.- Kinetics of the Addition of Tetracyanoethylene to Bis(Tertiary Phosphine)Bis(Isocyanide)Rhodium(I) Perchlorates.- Catalytic Applications of Oxidative Addition of Alkyl Halides to Transition Metal Complexes.- Organic Synthesis via Organotransition Metals.- Phosphine-Nickel Complexes as Catalysts for Cross-Coupling Reaction of Grignard Reagents with Vinylic, Aromatic and Heteroaromatic Halides.- Mechanisms of Thermal Decomposition of Transition Metal Organometallic Compounds.- Nickel(O) Catalyzed Reactions Involving Strained a-Bonds.- Some Synthetic Reactions by Means of Nickel Carbonyl and Organic Halides.- Selective and Asymmetric Reductions of Carbonyl Compounds Using Hydrosilylation Catalyzed by Rhodium(I) Complexes.- Carbonylation Reactions of Organic Halides by Tetrakis(triphenylphosphine)nickel(O) and Palladium(O) Carbonyl Complexes under Mild Conditions.- The Palladium Catalyzed Reactions for Synthesis of Amines and Benzofurans.- Chemistry of Alkylnickel Complexes. Preparation and Properties of Alkylnickels with Tertiary Phosphine Ligands.- Studies of Hydrido Transition Metal Cluster Complexes.- A Facile Formation of ?-Allylplatinum(II) Complexes by Decarboxylation of Allyloxycarbonylplatinum(II) Complexes.- Optical Inversion and Substitution of Coordinated Olefins in Optically Active trans(N)-Chloro-L-prolinato-olefin-platinum(II) Complexes in Organic Solvents.- Conformational Equilibria and Stereospecific Synthesis.- Biological and Related Aspects.- Synthetic Models for the Oxygen-Binding Hemoproteins.- Organorhodium and Iridium Porphyrin Complexes a Model for Vitamin B12.- Unusual Metalloporphyrins.- The Catalyzed Reduction of Nitric Oxide by Carbon Monoxide using Soluble Rhodium Complexes.- Mechanisms for the Biosynthesis and Neurotoxicity of Methylmercury.- List of Authors.
Springer US; December 2012
392 pages; ISBN 9781468421422
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Title: Organotransition-Metal Chemistry
Author: Yoshio Ishii
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