Neighboring Group Participation

Volume 1 Withdrawn

Brian Capon,

Neighboring Group Participation: Volume 1 Withdrawn
 
 
1. General Considerations.- 1. Introduction.- 1.1. Historical and General Description of Neighboring Group Effects.- 1.2. Terms and Definitions.- 2. Some Factors that Influence Anchimeric Assistance.- 2.1. The Stabilities of Bridged Carbocations—Some Molecular Orbital Calculations.- 2.2 Hyperconjugation—An Alternative Explanation?.- 2.3. The Effect of Intramolecularity—Ring Size and gew-Dialkyl Effects.- 2.3.1. Ring Size.- 2.3.2. The gem-Dialkyl Effect.- 3. Some Experimental Methods Used in the Study of Neighboring Group Participation.- 3.1. Kinetic Methods.- 3.1.1. Estimation of Reaction Rates.- 3.1.2. Participation as a Function of Electron Demand.- 3.1.3. Kinetic Isotope Effects.- 3.2. Investigation of Solvent Effects.- 3.3. Isolation or Trapping of Intermediates.- 3.4. Spectroscopic Observation of Intermediates.- 3.5. Product Analysis.- 2. Participation by Simple Oxygen, Sulfur, and Nitrogen Groups.- 4. Participation by Oxygen Groups.- 4.1. Ether Groups.- 4.1.1. In Solvolytic Displacement Reactions.- 4.1.2. In Reactions at Carbonyl Carbon.- 4.1.3. In Electrophilic Addition Reactions.- 4.2. Hydroxyl Groups.- 4.2.1. In Solvolytic Displacement Reactions.- 4.2.2. In Addition Reactions.- 4.2.3. In Elimination Reactions.- 4.2.4. In Hydrolysis and Related Reactions.- 4.2.5. In Reduction Reactions.- 4.3. Hydroperoxide Groups.- 4.4. Oxime Groups.- 5. Participation by Sulfur Groups.- 5.1. Thioether Groups.- 5.1.1. In Solvolytic Displacement Reactions.- 5.1.2. In Electrophilic Addition Reactions.- 5.1.3. In Elimination Reactions.- 5.1.4. In Free-radical, Carbene, and Photochemical Reactions.- 5.2. Thiol Groups.- 6. Participation by Nitrogen Groups.- 6.1. Amino Groups.- 6.1.1. Anchimeric Assistance in Ring Closure Reactions.- 6.1.2. R2N-3 Participation.- 6.1.3. R2N-4 Participation.- 6.1.4. R2N-5 and R2N-6 Participation.- 6.1.5. Miscellaneous Modes of Participation.- 6.2. Nitrile Groups.- 6.3. Hydrazone Groups.- Author Index.


  • ;
  • ISBN:
  • Edition:
  • Title:
  • Series:
  • Author:
  • Imprint:
  • Language:

In The Press


About The Author


Customer Reviews

Verified Buyer

Read online

If you’re using a PC or Mac you can read this ebook online in a web browser, without downloading anything or installing software.

Download file formats

This ebook is available in file types:

This ebook is available in:

After you've bought this ebook, you can choose to download either the PDF version or the ePub, or both.

DRM Free

The publisher has supplied this book in DRM Free form with digital watermarking.

Required software

You can read this eBook on any device that supports DRM-free EPUB or DRM-free PDF format.

Digital Rights Management (DRM)

The publisher has supplied this book in encrypted form, which means that you need to install free software in order to unlock and read it.

Required software

To read this ebook on a mobile device (phone or tablet) you'll need to install one of these free apps:

To download and read this eBook on a PC or Mac:

  • Adobe Digital Editions (This is a free app specially developed for eBooks. It's not the same as Adobe Reader, which you probably already have on your computer.)

Limits on printing and copying

The publisher has set limits on how much of this ebook you may print or copy. See details.

  • {{ format_drm_information.format_name }} unrestricted {{ format_drm_information.format_name }} {{format_drm_information.page_percent}}% pages every day{{format_drm_information.interval}} days {{ format_drm_information.format_name }} off
Read Aloud
  • {{ read_aloud_information.format_name }} on {{ read_aloud_information.format_name }} off
Subject categories
  •  > 
ISBNs